Acid oceans

From WikiCover

Carbon emissions from human activities are not just heating up the globe, they are changing the ocean's chemistry. This could soon be fatal to coral reefs, which are havens for marine biodiversity and underpin the economies of many coastal communities. Scientists from the Carnegie Institution's Department of Global Ecology have calculated that if current carbon dioxide emission trends continue, by mid-century 98% of present-day reef habitats will be bathed in water too acidic for reef growth. Among the first victims will be Australia's Great Barrier Reef, the world's largest organic structure.

Chemical oceanographers Ken Caldeira and Long Cao presented their results in a multi-author paper in the December 14, 2007 issue of Science and at the annual meeting of American Geophysical Union in San Francisco. The work is based on computer simulations of ocean chemistry under levels of atmospheric CO2 ranging from 280 parts per million (pre-industrial levels) to 5000 ppm. Present levels are 380 ppm and rapidly rising due to accelerating emissions from human activities, primarily the burning of fossil fuels.

The absorbed CO2 produces carbonic acid, the same acid that gives soft drinks their fizz, making certain minerals called carbonate minerals dissolve more readily in seawater. This is especially true for aragonite, the mineral used by corals and many other marine organisms to grow their skeletons.

"Before the industrial revolution, over 98% of warm water coral reefs were bathed with open ocean waters 3.5 times supersaturated with aragonite, meaning that corals could easily extract it to build reefs," says Cao. "But if atmospheric CO2 stabilizes at 550 ppm -- and even that would take concerted international effort to achieve -- no existing coral reef will remain in such an environment." The chemical changes will impact some regions sooner than others. At greatest risk are the Great Barrier Reef and the Caribbean Sea.